Vinyl Polymerization. LXXIV. Radical Polymerization of Bornyl and Isobornyl Methacrylate
نویسندگان
چکیده
منابع مشابه
Horseradish peroxidase mediated free radical polymerization of methyl methacrylate.
This paper reports the free radical polymerization of methyl methacrylate (MMA) catalyzed by horseradish peroxidase (HRP). A novel method was developed whereby MMA polymerization can be carried out at ambient temperatures in the presence of low concentrations of hydrogen peroxide and 2,4-pentanedione in a mixture of water and a water-miscible solvent. Polymers of MMA formed were highly stereore...
متن کاملAnionic Vinyl Polymerization
The concept of anionic polymerization was first developed by Ziegler and Schlenk in early 1910. Their pioneering work on the polymerization of diene initiated with sodium metal set the stage for the use of alkali metal containing aromatic hydrocarbon complexes as initiators for various α-olefins. In 1939, Scott and coworkers used for the first time the alkali metal complexes of aromatic hydroca...
متن کاملCompression, supramolecular organization and free radical polymerization of ethylene gas
At low pressure, ethylene gas consists of single translating and rotating molecules and behaves as an ideal gas. With decrease of free volume by compression, various rotating supramolecular particles are formed, which require less space for the movement: molecular pairs, bimolecules and oligomolecules. The appearance of a new kind of particles is manifested as a phase transition of the second o...
متن کاملApplication of Genetic Algorithm to Determine Kinetic Parameters of Free Radical Polymerization of Vinyl Acetate by Multi-objective Optimization Technique
A Multi-objective optimization procedure has been developed to determine some kinetic parameters of free radical polymerization of vinyl acetate based on genetic algorithm. For this purpose, mathematical modeling of free radical polymerization of vinyl acetate is carried out first and then selected kinetic parameters are optimized by minimizing objective functions defined from comparing exp...
متن کاملMethylenelactide: vinyl polymerization and spatial reactivity effects
The first detailed study on free-radical polymerization, copolymerization and controlled radical polymerization of the cyclic push-pull-type monomer methylenelactide in comparison to the non-cyclic monomer α-acetoxyacrylate is described. The experimental results revealed that methylenelactide undergoes a self-initiated polymerization. The copolymerization parameters of methylenelactide and styr...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1963
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.66.7_992